Filling a Gap: Electrochemical Property Comparison of the Completed Compound Series [Mo2(DArF)n(O2C-Fc)4
By Cai, Xu-Min; Meister, Teresa K.; P
Published in Inorganic Chemistry
NULL
2016
Abstract
The reaction of cis-[Mo2(O2C-Fc)2(NCCH3)4][BF4]2 (cis-1) with two electronically different N,N?-diarylformamidinate (DArF) ligands (DArF = N,N?-bis(p-trifluoromethylphenyl)formamidinate (DTfmpF), N,N?-bis(p-anisyl)formamidinate (DAniF)) results in the isolation of the tris- and monosubstituted complexes [Mo2(DTfmpF)3(O2C-Fc)] (2a) and [Mo2(DAniF)(O2C-Fc)3] (2b). These complexes complete the series of [Mo2(DArF)n(O2C-Fc)4
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