Highly stable bilayer of LiPON and \B2O3\ added Li1.5Al0.5Ge1.5(PO4) solid electrolytes for non-aqueous rechargeable Li-O2 batteries
By Harsharaj S. Jadhav and Ramchandra S. Kalubarme and Arvind H. Jadhav and Jeong Gil Seo
Published in Electrochimica Acta
NULL
2016
Abstract
Lithium ion conducting membranes are barely studied, although they are essentially indispensable for building Li-air batteries composed of aqueous and non-aqueous electrolytes for long-term operation. Lithium phosphorous oxynitride (LiPON) thin films were deposited by RF-sputtering technique on B2O3-added lithium aluminum germanium phosphate (B-LAGP). Compact thin amorphous LiPON layer could act as a protective interlayer for B-LAGP by separating it from Li metal electrode and mitigate the reaction between them. Large electrochemical stability window (0
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