The electrooxidation of borohydride: A mechanistic study on palladi

By Grimmer, Christoph; Grandi, Maximilian; Zacharias, Robert; Cermenek, Bernd; Weber, Hansjorg; Morais, Claudia; Napporn, Teko W.; Weinberger, Stephan; Schenk, Alexander & Hacker, Viktor
Published in Applied Catalysis B: Environmental NULL 2015

Abstract

Electrochemical borohydride oxidation reaction, intermediates and reaction products are studied by cyclic voltammetry with rotating disk electrodes, chronoamperometry coupled with 11B NMR spectroscopy and in-situ FTIR measurements. Depending on the electrode potential of a Pd/C catalyst on a rotating disk electrode the n

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