Synthesis, Structures, and Photophysical Properties of a Series of Rare Near-IR Emitting Copper(I) Complexes
By Hupp, Benjamin; Schiller, Carl; Lenczyk, Carsten; Stanoppi, Marco; Edkins, Katharina; Lorbach, Andreas; Steffen, Andreas
Published in Inorganic Chemistry
2017
Abstract
Herein, we report on the synthesis and structural characterization of a series of trigonal and tetrahedral cationic copper(I) complexes, bearing phosphine or N-heterocyclic carbene ligands as donors, with benzthiazol-2-pyridine (pybt) and benzthiazol-2-quinoline (qybt) acting as ?-chromophores. The compounds are highly colored due to their 1MLCT (MLCT = metal-to-ligand charge transfer) states absorbing between ca. ?abs = 400
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