Co-Poly(ionic liquid) Films via Anion Exchange for the Continuous Tunability of Ion Transport and Wettability
By Njoroge, Ian; Bout, Brandon W.; Matson, Maxwell W.; Laibinis, Paul E.; Jennings, G. Kane
Published in ACS Omega
2018
Abstract
This manuscript details a novel and simple approach to achieve surface-tethered co-poly(ionic liquid) (coPIL) films through the exchange of the resident anion of a poly(ionic liquid) (PIL) film with two or more anions. Initially, surface-tethered PIL films were prepared by the surface-initiated ring-opening metathesis polymerization of the ionic liquid monomer 3-[(bicyclo[2.2.1]hept-5-en-2-yl)methyl]-1,2-dimethylimidazol-3-ium hexafluorophosphate ([N1-dMIm][PF6]) whose PF6
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