Active, durable bismuth oxide-manganite composite oxygen electrodes: Interface formation induced by cathodic polarization

By Chen, Minle; Cheng, Yi; He, Shuai; Ai, Na; Veder, Jean-Pierre; Rickard, William D. A.; Saunders, Martin; Chen, Kongfa; Zhang, Teng; Jiang, San Ping
Published in Journal of Power Sources 2018

Abstract

Bismuth oxide is as an active promoter in enhancing the ionic conductivity and electrocatalytic activity of manganite oxygen electrodes of solid oxide cells, but there are very limited reports on the formation and evolution of electrode/electrolyte interface of bismuth oxide-manganite composite electrode under the influence of electrochemical polarization. Herein, we report the effect of electrochemical polarization and direction of polarization current on the electrocatalytic performance and electrode/electrolyte interface of a (La0

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