Structural insights on understanding the cubic phase stabilization mechanism of sol-gel synthesized Li7-3xAlxLa3Zr2O12 (x = 0

By Dermenci, Kamil Burak; Turan, Servet
Published in Ceramics International 2018

Abstract

Stabilization of cubic Li7La3Zr2O12 phase, one of the most promising solid electrolytes for Li-ion batteries, has been extensively studied in terms of various stabilizer additions in solution-based systems. However, different dissociation behavior of precursors on the cubic LLZO phase stabilization has not been studied. In this study, we offer an understanding for the stabilization of cubic Li7La3Zr2O12 phase by using ZrOCl2 and ZrO(NO3)2, which are having different dissociation behavior, with 0

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