Morphology-Controlled One-Step Synthesis of Nanostructured LiNi1/3Mn1/3Co1/3O2 Electrodes for Li-Ion Batteries

By Wang, Yang; Roller, Justin; Maric, Radenka
Published in ACS Omega 2018

Abstract

Nanostructured electrodes effectively enhance the kinetics of the charge/discharge process in lithium-ion (Li-ion) batteries. However, the fabrication of these electrodes often involves complex processing steps. This study demonstrates a one-step improved flame spray pyrolysis synthesis approach to directly deposit the most common Li-ion battery cathode material LiNi1/3Mn1/3Co1/3O2 onto current collectors, which is identified as reactive spray deposition technology (RSDT). Because of the economical and continuous nature of RSDT, the industrial scale of manufacturing nanostructured electrodes for Li-ion batteries can be potentially developed. Morphologies of the electrodes are well controlled so that their electrochemical properties can be tailored to accommodate intended applications. In detail, by adjusting the precursor concentration in the solution feed during the operation of RSDT, the specific surface area of synthesized material can be fine-tuned accordingly. Although the electrodes prepared with low precursor concentration exhibit the highest surface area and deliver the highest initial discharge capacity of 192.1 mAh g

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