Flexible, silver nanowire network nickel hydroxide core-shell electrodes for supercapacitors

By Yuksel, Recep; Coskun, Sahin; Kalay, Yunus Eren; Unalan, Husnu Emrah
Published in Journal of Power Sources NULL 2016

Abstract

Abstract We present a novel one-dimensional coaxial architecture composed of silver nanowire (Ag NW) network core and nickel hydroxide (Ni(OH)2) shell for the realization of coaxial nanocomposite electrode materials for supercapacitors. Ag {NWs} are formed conductive networks via spray coating onto polyethylene terephthalate (PET) substrates and Ni(OH)2 is gradually electrodeposited onto the Ag {NW} network to fabricate core-shell electrodes for supercapacitors. Synergy of highly conductive Ag {NWs} and high capacitive Ni(OH)2 facilitate ion and electron transport, enhance electrochemical properties and result in a specific capacitance of 1165.2 F g?1 at a current density of 3 A g?1. After 3000 cycles, fabricated nanocomposite electrodes show 93% capacity retention. The rational design explored in this study points out the potential of nanowire based coaxial energy storage devices.

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