Electrochemical stability of carbon-supported gold nanoparticles in acidic electrolyte during cyclic voltammetry

By Steven, Jared T.; Golovko, Vladimir B.; Johannessen, Bernt; Marshall, Aaron T.
Published in Electrochimica Acta NULL 2016

Abstract

Abstract Cyclic voltammetry has been used to assess the electrochemical stability of gold nanoparticle-based electrocatalysts with differing initial particle size distributions in sulphuric acid electrolyte. The electrochemically active surface area (EASA), based on the gold oxide reduction charge, revealed that the electrocatalyst containing gold nanoparticles with an initial number-weighted average diameter of 4.5 nm was stable over 100 voltammetry cycles. Conversely, the electrocatalysts based on 3.1 nm and 2.9 nm gold nanoparticles showed a continuous decrease in the {EASA} in line with {TEM} and {EXAFS} data which confirmed growth of the gold particles during cycling. Importantly, we find no evidence to suggest that the nature of the stabilising ligand used during the gold nanoparticle synthesis, has any effect of the electrochemical stability of gold nanoparticles. When the anodic limit of the cyclic voltammograms was limited to below the gold oxide formation potential, the nanoparticles were stable, confirming that the loss in {EASA} is primarily related to the dissolution and growth of gold nanoparticles associated with the Au-AuOx redox process. Interestingly, an electrocatalyst initially containing 0.8 nm diameter gold nanoclusters had a surprisingly low {EASA} (these clusters appear not to exhibit normal Au-AuOx redox behaviour typical for the larger gold nanoparticles), but still showed significant particle growth during the cycling as confirmed by {TEM} and {XPS} analysis.

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