Electrochemical Properties and CO2-Reduction Ability of m-Terphenyl Isocyanide Supported Manganese Tricarbonyl Complexes
By Agnew, Douglas W.; Sampson, Matthew D.; Moore, Curtis E.; Rheingold, Arnold L.; Kubiak, Clifford P.; Figueroa, Joshua S.
Published in Inorganic Chemistry
2016
Abstract
To circumvent complications with redox-active ligands commonly encountered in the study of manganese electrocatalysts for CO2 reduction, we have studied the electrochemistry of the manganese mixed carbonyl/isocyanide complexes XMn(CO)3(CNArDipp2)2 (X = counteranion), to evaluate the pairing effects of the counteranion and their influence over the potential necessary for metal-based reduction. The complexes described herein have been shown to act as functional analogues to the known homoleptic carbonyl manganese complexes [Mn(CO)5]n (n = 1
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