Enhanced photoelectrochemical detection of l-cysteine based on the ultrathin polythiophene layer sensitized anatase TiO2 on F-doped tin oxide substrates

By Yuqiao Wang and Wei Wang and Shasha Wang and Wenjing Chu and Tao Wei and Haijun Tao and Chuanxiang Zhang and Yueming Sun
Published in Sensors and Actuators B: Chemical NULL 2016

Abstract

An effective photoelectrochemical (PEC) detection methodology was established and used to determine l-cysteine based on the ultrathin polythiophene layer sensitized anatase TiO2 on F-doped tin oxide substrates (PTh/TiO2/FTO). The PTh/TiO2 core-shell composites were synthesized by in situ polymerization of thiophene on TiO2 nanoparticle surfaces, resulting in a 1-nm-thick \PTh\ layer decorated TiO2. The ultrathin layer could improve the electronic conductivity and enhance the light absorption, indicating that the PTh/TiO2/FTO electrode might strengthen a weak electrical signal response in detecting the low concentration of l-cysteine. Under Xe light of 25 mW cm?2, the \PEC\ detection limit of l-cysteine was 12.8 ?M from the transient photocurrent response method (linear range: 0.1

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