Solution processing of TiO2 compact layers for 3rd generation photovoltaics

By Cecile Charbonneau and Petra J. Cameron and Adam Pockett and Anthony Lewis and Joel R. Troughton and Eifion Jewell and David A. Worsley and Trystan M. Watson
Published in Ceramics International NULL 2016

Abstract

In this study, we introduce a new method for the deposition of TiO2 compact layers which involves the deposition of a wet film of an inorganic titanium (IV) precursor followed by fast hydrolytic conversion to crystalline TiO2 under near infrared radiative (NIR) treatment. With this, we aim to provide a scalable alternative to methods conventionally employed in laboratories for the fabrication of 3rd generation photovoltaic devices, such as high temperature pyrolysis or spin coating of organic titanium (IV) precursors. Optimization of our solution process is presented in detail. Structural features and crystalline properties of solution processed compact layers are characterized by FEG-SEM imaging and x-ray diffraction analyses and compared to compact layers produced by conventional laboratory techniques. Minimization of electron recombination is evaluated in standard liquid I?/ I 3 - dye-sensitized solar cells (DSC). The results show that a compact, homogenous, high coverage yield crystalline TiO2 anatase layer can be produced by sequential deposition of 2

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