Rapid and Efficient Redox Processes within 2D Covalent Organic Framework Thin Films
By DeBlase, Catherine R.; Hernandez-Burgos, Kenneth; Silberstein, Katharine E.; Rodriguez-Calero, Gabriel G.; Bisbey, Ryan P.; Abruna, Hector D. & Dichtel, William R.
Published in ACS Nano
NULL
2015
Abstract
Two-dimensional covalent organic frameworks (2D COFs) are ideally suited for organizing redox-active subunits into periodic, permanently porous polymer networks of interest for pseudocapacitive energy storage. Here we describe a method for synthesizing crystalline, oriented thin films of a redox-active 2D COF on Au working electrodes. The thickness of the COF film was controlled by varying the initial monomer concentration. A large percentage (80-99\%) of the anthraquinone groups are electrochemically accessible in films thinner than 200 nm, an order of magnitude improvement over the same COF prepared as a randomly oriented microcrystalline powder. As a result, electrodes functionalized with oriented COF films exhibit a 400% increase in capacitance scaled to electrode area as compared to those functionalized with the randomly oriented COF powder. These results demonstrate the promise of redox-active COFs for electrical energy storage and highlight the importance of controlling morphology for optimal performance.
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