Electrochemical Proton Reduction and Equilibri
By Bentley, Cameron L.; Bond, Alan M.; Hollenkamp, Anthony F.; Mahon, Peter J. & Zhang, Jie
Published in The Journal of Physical Chemistry C
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2015
Abstract
Many organic compounds contain acidic and/or basic groups that dictate their physical, chemical, and biological properties. For this reason, the acid dissociation constant, Ka, a quantitative measure of acid strength in solution, is a fundamentally important parameter in organic (synthetic) chemistry and related fields. In this study, the thermodynamics, kinetics, and mechanisms of the proton reduction (hydrogen evolution) reaction at a platin
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