Effect of alumina addition on the electrical and mechanical properties of Ce₀.₈Gd₀.₂O₂₋δ ceramics

By Tianshu Zhang,Zhiqiang Zeng, Haitao Huang, Peter Hing, J Kilner
Published in Materials Letters NULL 2002

Abstract

(1−x) Ce₀.8Gd₀.₂O₂−δ+x Al₂O₃ ceramics with compositions x=0 to 0.2 were prepared by the conventional mixed-oxide method from high purity (>99.9%) of commercial powders, and sintered at 1550 °C for 5 h in air. Sintered density, crystal phase, and microstructure were characterized. The ionic conductivity was measured over 200 to 800 °C in air using an impedance analyzer in the frequency range of 0.001 to 100 Hz. Microhardness and indentation fracture toughness were also determined. A new phase (i.e., GdAlO3) has been detected in the samples with Al content greater than 5% AlO₁.₅. Ce₀.₈Gd₀.₂O₂₋δ ceramic has a Vickers hardness of ∼9.23±0.15 GPa, and an indentation fracture toughness of ∼1.47±0.2 MPa m¹´². A remarkable improvement in both fracture toughness and microhardness can be observed for the samples with over 10% AlO₁.₅. However, the addition of Al2O3 exhibits a detrimental effect on the conductivities, especially on grain boundary conductivity, which is possibly related to the formation of GdAlO3.

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