Role of amines and amino acids in enhancing the removal rates of undoped and P-doped polysilicon films during chemical mechanical polishing

By Veera Dandu, P.R.; Peethala, B.C.; Penta, Naresh K. & Babu, S.V.
Published in Colloids and Surfaces A: Physicochemical and Engineering Aspects NULL 2010

Abstract

During chemical mechanical polishing, removal rates of undoped and P-doped polysilicon films as high as 200 and 250 nm/min, respectively, have been achieved using several abrasive-free solutions, each consisting of an amine or amino acid. It was observed that only α-amine(s) solutions enhance the removal rates of both undoped and P-doped polysilicon films. Potentiodynamic, zeta potential, contact angle, thermo gravimetric and EDS measurements were performed to examine the role of these α-amines in achieving high polysilicon removal rate. Possible removal mechanism of both undoped and P-doped polysilicon film in the presence and absence of the different additives is also proposed.

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