Synthesis and characterization of [FeFe]-hydrogenase models mediated by a 1,2,4-trithiolane derivative: Insight into molecular structures and electrochemical characteristics
By Abul-Futouh, Hassan; Daraosheh, Ahmad Q.; Windhager, Jochen; G
Published in Polyhedron
2019
Abstract
In this report two diiron hexacarbonyl complexes containing sulphur-rich heterocycles have been prepared as [FeFe]-hydrogenase mimics. These two complexes are obtained from the reaction of Fe3(CO)12 with 3,11-dibenzyl-7,14,15-trithia-3,11-diazadispiro[5.1.58.26]pentadecane. They have been characterized by different spectroscopic techniques (1H and 13C1H NMR, IR and MS) as well as X-ray diffraction analysis. Moreover, we have investigated the influence of the sulphur-rich heterocycles linker on the redox potentials of the complexes and their catalytic ability in the presence of acetic acid (AcOH) by applying cyclic voltammetry.
Microsoft is Ending Support for Windows 7
Microsoft will discontinue support for Windows 7 on January 14, 2020 which means Gamry will also be discontinuing support for Windows 7. If you are upgrading to Windows 10, like many companies and institutions, you need to be running Version 7 of our s oftware . Please note that only USB and Ethernet-based instruments can run in Version 7. Eligible users can download the latest version of our software through our online Client Portal .
If you haven't already registered your instrument, you can do so through the Client Portal .
Please email Technical Support if you have any questions regarding this transition. Please be sure to include your instrument model and serial number when contacting us.